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　　理學(xué)院可見光誘導(dǎo)催化的有機合成方法學(xué)報告

　　題目：Visible-Light-Driven Fine Chemical Synthesis Using Inexpensive Natural Gases and Hydrocarbons as Feedstocks in Batch and Flow Reactors

　　報告人：吳杰博士，新加坡國立大學(xué)化學(xué)系tenure-tracked助理教授，博士生導(dǎo)師

　　時間：2018年12月27日，14點30分

　　地點：理學(xué)院報告廳

　　歡迎廣大師生參加!

　　專家介紹：

　　吳杰博士，新加坡國立大學(xué)化學(xué)系tenure-tracked助理教授，博士生導(dǎo)師。

　　教育工作經(jīng)歷：

　　?2006年6月，本科畢業(yè)于北京師范大學(xué)化學(xué)系

　　?2012年5月，博士畢業(yè)于美國波士頓大學(xué)，師從James S. Panek教授從事天然產(chǎn)物全合成研究，期間加入波士頓大學(xué)化學(xué)方法和分子庫研究中心，在John A. Porco教授的指導(dǎo)下完成多樣導(dǎo)向合成的課題

　　?2012年7月-2015年1月，美國麻省理工學(xué)院(MIT)化學(xué)系和化工系聯(lián)合培養(yǎng)的博士后，師從Timothy F. Jamison教授和T. Alan Hatton教授從事連續(xù)流動合成的研究;

　　?2015年5月-至今，新加坡國立大學(xué)化學(xué)系，tenure-tracked的助理教授，博士生導(dǎo)師。

　　研究領(lǐng)域：

　　課題組集中于發(fā)展新的可見光誘導(dǎo)的催化方法學(xué)，以天然氣體或者便宜易得的C-H和Si-H鍵化合物作為原料，合成具有高附加值的化學(xué)品;并同時利用微型流體管路反應(yīng)器和開發(fā)新的反應(yīng)器模式增強光照反應(yīng)的效率，實現(xiàn)傳統(tǒng)化學(xué)條件下難以達到的反應(yīng)環(huán)境。在迄今三年時間內(nèi)，并先后在J. Am. Chem. Soc.、Angew Chem. Int. Ed.、Chem、ACS Catal.、Chem. Sci.等雜志上發(fā)表論文19篇，申請專利2項，其中多篇文章被Angew Chem. Int. Ed.，Synfacts，X-MOL，WeeChem等所評述。

　　個人榮譽：

　　?03/2017, the 4th Green & Sustainable Manufacturing Award from GSK-EDB

　　?11/2017, Asian Core Program Lectureship Award from China in the 12th International Conference on Cutting-Edge Organic Chemistry in Asia (ICCEOCA-12).

　　?09/2018, the Department Young Chemist Award 2018 from Department of Chemistry, National University of Singapore.

　　?11/2018, Asian Core Program Lectureship Award from Taiwan and Thailand in the 13th International Conference on Cutting-Edge Organic Chemistry in Asia (ICCEOCA-13)

　　?11/2018, Thieme Chemistry Journal Award (2019)

　　發(fā)表文章的代表作：

　　1.Xue, F.?; Deng, H.?; Xue, C.; Mohamed, D. K. B.; Tang, K. Y.; Wu, J.* “Reaction Discovery Using Acetylene Gas as the Chemical Feedstock Accelerated by the ‘Stop-Flow’ Micro-Tubing Reactor System” Chem. Sci. 2017, 8, 3623-3627. (?Co-first authors)

　　2. Zhou, R.; Liu, H.; Tao, H.; Yu, X.; Wu, J.* Metal-free direct alkylation of unfunctionalized allylic/benzylic sp3 C–H bonds via photoredox induced radical cation deprotonation. Chem. Sci. 2017, 8, 4654-4659.This article was featured in Synfacts.

　　3. Deng, H.; Fan, X.; Chen, Z.; Xu, Q.; & Wu, J.* Photo-induced nickel-catalyzed chemo- and regioselective hydroalkylation of internal alkynes with ether and amide a-hetero C(sp3)-H bonds J. Am. Chem. Soc. 2017, 139, 13579-13584.This work was highlighted by NUS FoS,Phys.org and X-MOL.

　　4. Zhou, R.; Goh, Y. Y.; Liu, H.; Tao, H.; Li, L.; Wu, J.* “Visible-Light-Mediated Metal-Free Hydrosilylation of Alkenes through Selective Hydrogen Atom Transfer for Si-H Activation” Angew. Chem. Int. Ed. 2017, 56, 16621-16625.This article was featured in Synfacts and X-MOL.

　　5. Hou, J., Ee, A., Feng, W., Xu, J.-H., Zhao, Y.,* Wu, J.* Visible-Light-Driven Alkyne Hydro-/Carbocarboxylation Using CO2 via Iridium/Cobalt Dual Catalysis for Divergent Heterocycle Synthesis J. Am. Chem. Soc.2018, 140, 5257-5263. This work was highlighted by X-MOL.

　　6. Fan, X.-Z., Rong, J.-W., Wu, H.-L., Zhou, Q., Deng, H.-P., Tan, J. D., Xue, C.-W., Wu, L.-Z., Tao, H.-R., Wu, J.* Eosin Y as a Direct Hydrogen Atom Transfer Photocatalyst for the Functionalization of C-H Bonds Angew. Chem. Int. Ed. 2018, 57, 8514-8518. This paper has been selected as Hot Topic in Organocatalysis and Photocatalysis.This work was highlighted by Angew. Chem. Int. Ed. (Prof. Chen Jiarong and Prof. Xiao Wenjing) and X-MOL.

　　7. Liu, H., Ma, L., Zhou, R., Chen, X.,* Fang, W., Wu, J.* One-Pot Photo-Mediated Giese Reaction/Friedel-Crafts Hydroxyalkylation/Oxidative Aromatization to Access Naphthalene Derivatives from Toluenes and Enones ACS Catal. 2018, 8, 6224-6229. This paper was highlighted by X-MOL.

　　8. Deng, H.-P., Zhou, Q., Wu, J.* Micro-Tubing Reactor-Assisted Aliphatic C-H Functionalization Utilizing HCl as the Hydrogen Atom Transfer Catalyst Precursor in Conjunction with an OrganoPhotoredox Catalyst Angew. Chem. Int. Ed.2018, 57,12661-12665. This paper was highlighted by X-MOL.

　　9. Li, J., Luo Y., Cheo, H. W., Lan, Y.,* Wu, J.* Photoredox Catalysis Modulated Nickel-Catalyzed Divergent Difunctionalization of Ethylene Chem2018, DOI: 10.1016/j.chempr.2018.10.006.

　　10. Hou, J., Ee, A., Cao, H., Ong, H.-W., Xu, J.-H. Wu, J.* Visible‐Light‐Mediated Metal‐Free Difunctionalization of Alkenes with CO2 and Silanes or C(sp3)-H Alkanes Angew. Chem. Int. Ed. 2018, 57, 17220-17224.This paper has been selected as Hot Paper by Angew. Chem. Int. Ed (Topics: C-H Activation, Carbon Dioxide, and Photocatalysis).This paper was highlighted by X-MOL and WeeChem.

　　11. Cao, H., Jiang, H., Feng, H., Kwan, J. M. C., Liu, X., Wu, J.* Photo-Induced Decarboxylative Heck-Type Coupling of Unactivated Aliphatic Acids and Terminal Alkenes in the Absence of Sacrificial Hydrogen Acceptors J. Am. Chem. Soc.2018, 140, 16360-16367.

　　12. Ng, C. K., Toh, R. W., Lin, T. T., Luo, H.-K., Hor, T. S. A.,* Wu, J.* Metal-salen molecular cages as efficient and recyclable heterogeneous catalysts for cycloaddition of CO2 with epoxides at ambient conditions Chem. Sci.2019, DOI: 10.1039/C8RE00216A.

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